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Nickel nanopore arrays as promising current collectors for constructing solid-state supercapacitors with ultrahighrate performance

Huaping Zhao, Long Liu, Yaoguo Fang, Ranjith Vellacheri, Yong Lei

《化学科学与工程前沿（英文）》 2018年 第12卷 第3期   页码 339-345 doi: 10.1007/s11705-018-1699-6

摘要：

In this work, nickel nanopore arrays with a highly-oriented nanoporous structure inherited from porous alumina membranes were used as nanostructured current collectors for constructing ultrahigh rate solid-state supercapacitors. A thin layer of poly(3,4-ethylenedioxythiophene) (PEDOT) as electroactive materials was conformally coated onto nickel nanopores to form heterostructured electrodes. The as-prepared electrodes have a large specific surface area to ensure a high capacity, and the highly-oriented nanoporous structure of nickel nanopores reduces the ion transport resistance, allowing the ions in the solid-state electrolytes to quickly access the PEDOT surface during the fast charge-discharge process. As a result, the assembled solid-state supercapacitor in a symmetric configuration exhibits an ideal capacitive behavior and a superior rate capability even at an ultrahigh scan rate of 50 V·s−1.

关键词： supercapacitor     ultrahigh rate     metallic nanopore arrays     current collectors     PEDOT    

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of a superhydrophilic/underwater superoleophobic stainless steel mesh for oil/water separation with ultrahigh

《化学科学与工程前沿（英文）》 2023年 第17卷 第1期   页码 46-55 doi: 10.1007/s11705-022-2170-2

摘要： Because of the increasing amount of oily wastewater produced each day, it is important to develop superhydrophilic/underwater superoleophobic oil/water separation membranes with ultrahigh flux and high separation efficiency. In this paper, a superhydrophilic/underwater superoleophobic N-isopropylacrylamide-coated stainless steel mesh was prepared through a simple and convenient graft polymerization approach. The obtained mesh was able to separate oil/water mixtures only by gravity. In addition, the mesh showed high-efficiency separation ability (99.2%) and ultrahigh flux (235239 L∙m–2∙h–1). Importantly, due to the complex cross-linked bilayer structure, the prepared mesh exhibited good recycling performance and chemical stability in highly saline, alkaline and acidic environments.

关键词： oil/water separation     N-isopropylacrylamide     stainless steel mesh     ultrahigh flux    

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Experimental and parametrical investigation of pre-stressed ultrahigh-performance fiber-reinforced concrete

《结构与土木工程前沿（英文）》 2023年 第17卷 第3期   页码 411-428 doi: 10.1007/s11709-023-0928-3

摘要： In this study, ultrahigh-performance fiber-reinforced concrete (UHPFRC) used in a type B70 concrete sleeper is investigated experimentally and parametrically. The main parameters investigated are the steel fiber volume fractions (0%, 0.5%, 1%, and 1.5%). Under European standards, 35 UHPFRC sleepers are subjected to static bending tests at the center and rail seat sections, and the screw on the fastening system is pulled out. The first cracking load, failure load, failure mode, crack propagation, load–deflection curve, load–crack width, and failure load from these tests are measured and compared with those of a control sleeper manufactured using normal concrete C50. The accuracy of the parametric study is verified experimentally. Subsequently, the results of the study are applied to UHPFRC sleepers with different concrete volumes to investigate the effects of the properties of UHPFRC on their performance. Experimental and parametric study results show that the behavior of UHPFRC sleepers improves significantly when the amount of steel fiber in the mix is increased. Sleepers manufactured using UHPFRC with a steel fiber volume fraction of 1% and a concrete volume less than 25% that of standard sleeper B70 can be used under the same loads and requirements, which contributes positively to the cost and surrounding environment.

关键词： pre-stressed concrete sleeper     ultrahigh performance fiber-reinforced concrete     pull-out test     static bending test     steel fiber     aspect ratio     volume fraction    

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超高压下的极端含能材料 Perspective

毛河光, 吉诚, 李冰, 刘罡, Eugene Gregoryanz

《工程（英文）》 2020年 第6卷 第9期   页码 976-980 doi: 10.1016/j.eng.2020.07.010

摘要：

含有极高能量密度的单键聚合氮和单原子金属氢，常被称为极端含能材料。虽然它们需要几百吉帕的超高压才能合成，并且难以直接应用，但是研究它们的稳定性、亚稳定性和其他基本特性，仍然对另辟蹊径寻找极端含能材料甚有价值。在100~200 GPa，已经发现了多种结晶态和非晶态的聚合氮。立方偏转结构聚合氮和黑磷结构聚合氮是两种特别有意思的聚合氮，它们的滞后保存现象提供了进一步探索氮应用的前景。另外，虽然金属氢被预估具有最高的能量密度，但预测只能保存皮秒（ps）的寿命和只能合成皮克（pg）的质量，还不是一个有实用可能性的材料。因此金属氢应被定位为一个兴趣导向的基础科研课题，主要聚焦压力下分子氢的晶体构造和电子结构的奇妙演化过程，即从低密度超宽能带的绝缘体，到窄能带的半导体，再到高密度的分子金属和原子金属，最后到前所未有的崭新物理态。这些挑战驱动着超高压科学和技术的持续创新和突破。

关键词： 含能材料     超高压     聚合氮     金属氢    

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Synthesis of micro/meso porous carbon for ultrahigh hydrogen adsorption using cross-linked polyaspartic

Jun Wei, Jianbo Zhao, Di Cai, Wenqiang Ren, Hui Cao, Tianwei Tan

《化学科学与工程前沿（英文）》 2020年 第14卷 第5期   页码 857-867 doi: 10.1007/s11705-019-1880-6

摘要： In addition to the specific surface area, surface topography and characteristics such as the pore size, pore size distribution, and micro/mesopores ratio are factors that determine the performance of porous carbons (PCs) in the fields of energy, catalysis, and adsorption. Based on the mechanism of weight loss of polyaspartic acid at high temperatures, this study provided a new method for adjusting the surface morphology of PCs by changing the cross-linking ratio of the precursor, where cross-linked polyaspartic acid was used as precursor without additional activating agents. N adsorption analysis indicated that the specific surface area of the obtained PCs was as high as 1458 m ·g , of which 1200 m ·g was the contribution of the microporous area and the highest pore volume was 1.13 cm ·g , of which the micropore volume was 0.636 cm ·g . The thermogravimetric analysis results of the precursor, and also the scanning electron microscopy and Brunauer–Emmet–Teller analysis results of the carbonization product confirmed that the prepared PCs presented multilevel pore structure, and the diameters of most pores were 0.78 and 3.97 nm; moreover, the pore size distribution was relatively uniform. This conferred the PCs the ultrahigh hydrogen adsorption capacity of up to 4.52 wt-% at 77 K and 1.13 bar, in addition to their great energy storage and catalytic potential.

关键词： porous carbon     multilevel pores     polyaspartic acid     cross-linking     hydrogen adsorption    

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Erratum to “Targeted Genotyping of a Whole-Gene Repertoire by an Ultrahigh-Multiplex and Flexible HD-Marker Erratum

Pingping Liu,Jia Lv,Cen Ma,Tianqi Zhang,Xiaowen Huang,Zhihui Yang,Lingling Zhang,Jingjie Hu,Shi Wang,Zhenmin Bao,

《工程（英文）》 2022年 第18卷 第11期   页码 259-259 doi: 10.1016/j.eng.2022.09.002

关键词： online     THE AUTHORS.Published     repertoire     behalf     Engineering     September     genotyping     Academy     HD-marker approach”     Education Press Limited Company.    

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Activated carbon-hybridized and amine-modified polyacrylonitrile nanofibers toward ultrahigh and recyclable

Fengli Li, Chuang Chen, Yuda Wang, Wenpeng Li, Guoli Zhou, Haoqin Zhang, Jie Zhang, Jingtao Wang

《化学科学与工程前沿（英文）》 2021年 第15卷 第4期   页码 984-997 doi: 10.1007/s11705-020-2000-3

摘要： Nanofibers with high specific surface area and chemical stability have broad prospects in the applications of adsorption. However, the adsorption capacity is limited by the scarcity of adsorption groups and storage space. Herein, the activated carbon-hybridized and amine-modified nanofibers are prepared by integrating activated carbon (AC) and polyacrylonitrile (PAN) via electrospinning method and the subsequent amination, which could provide additional storage space and adsorption groups for ultrahigh adsorption capability. Thus, the obtained amine-rich porous PAN nanofibers (APAN/AC) readily realized the ultrahigh adsorption capacity for metal ions and dyes in wastewater. Specifically, the adsorption capacity of APAN/AC nanofibers were 284 mg·g for Cr(VI) and 248 mg·g for methyl orange, which were almost 2 and 4 times than that of amine-modified nanofibers (APAN) and carbon-hybridized nanofibers (PAN/AC), respectively. Moreover, the AC inhibited the chain mobility of polymer matrix and thereby endowing APAN/AC nanofibers with excellent recyclability. The adsorption capability retained 80% after nine adsorption-desorption cycles. The adsorption kinetics and corresponding mechanism were further explored. This strategy combines the advantages of polymer nanofibers and AC, opening a new avenue for developing next-generation absorbent materials.

关键词： carbon-hybridized and amine-modified nanofibers     polyacrylonitrile     metal ions and dyes     wastewater     adsorption kinetics    

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The combined effects of biomass and temperature on maximum specific ammonia oxidation rate in domestic

《环境科学与工程前沿（英文）》 2021年 第15卷 第6期 doi: 10.1007/s11783-021-1411-9

摘要：

• Actual SAORs was determined using MLVSS and temperature.

关键词： Specific ammonia oxidation rate     Sequencing batch reactor     Biomass     Temperature coefficient     Model simulation    

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Use of float consumption rate in resource leveling of construction projects

Atilla DAMCI, Gul POLAT, Firat Dogu AKIN, Harun TURKOGLU

《工程管理前沿（英文）》 2022年 第9卷 第1期   页码 135-147 doi: 10.1007/s42524-020-0118-0

摘要： The management of resources has been claimed to be as important as scheduling methods. Inefficiency in managing resources may bring about severe delays and cost overruns caused by resource shortages in some cases and/or idle resources in others. Therefore, resources should be utilized efficiently to prevent project failures. Resource leveling is one of the approaches that are used for the management of resources. It aims to minimize fluctuations, peaks, and valleys in resource utilization without changing the completion time of a project and the number of resources required. Although the main principle behind traditional resource leveling is achieving an even flow of resources while the original project duration remains unchanged, the literature supports the need to develop an efficient model that discriminates among the activities that are selected for participation in resource leveling. For this purpose, this study has developed a model that considers the float consumption rates of activities in resource leveling. The float consumption rate is the percentage that is set to determine the maximum amount of float which will be consumed to shift the start time of the activity. The proposed model allows a scheduler to assign float consumption rates to each activity that can be used during the resource leveling procedure. When the required information is inputted, the proposed model automatically changes the required daily resources as it shifts the noncritical activities along their available total float times. The proposed model is expected to minimize the likelihood of severe delays and cost overruns. The model is demonstrated by constructing a network and its resource utilization histograms.

关键词： resource management     resource leveling     float consumption rate     scheduling    

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Effect of loading rate on shear strength parameters of mechanically and biologically treated waste

《环境科学与工程前沿（英文）》 2022年 第16卷 第12期 doi: 10.1007/s11783-022-1595-7

摘要：

● Mechanical behavior of MBT waste affected by loading rate was investigated.

关键词： Mechanically and biologically treated waste     Landfill     Triaxial test     Loading rate     Axial strain     Shear strength parameter    

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Size-controllable synthesis of monodispersed nitrogen-doped carbon nanospheres from polydopamine for high-rate

《化学科学与工程前沿（英文）》 2023年 第17卷 第11期   页码 1788-1800 doi: 10.1007/s11705-023-2326-8

摘要： Monodispersed nitrogen-doped carbon nanospheres with tunable particle size (100–230 nm) were synthesized via self-polymerization of biochemical dopamine in the presence of hexamethylenetetramine as a buffer and F127 as a size controlling agent. Hexamethylenetetramine can mildly release NH3, which in turn initiates the polymerization reaction of dopamine. The carbon nanospheres obtained exhibited a significant energy storage capability of 265 F·g–1 at 0.5 A·g–1 and high-rate performance of 82% in 6 mol·L–1 KOH (20 A·g–1), which could be attributed to the presence of abundant micro-mesoporous structure, doped nitrogen functional groups and the small particle size. Moreover, the fabricated symmetric supercapacitor device displayed a high stability of 94% after 5000 cycles, revealing the considerable potential of carbon nanospheres as electrode materials for energy storage.

关键词： carbon nanospheres     size-controlled     nitrogen-doped     high-rate     supercapacitors    

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Improved rate-based modeling of carbon dioxide absorption with aqueous monoethanolamine solution

Stefania MOIOLI, Laura A. PELLEGRINI, Simone GAMBA, Ben LI

《化学科学与工程前沿（英文）》 2014年 第8卷 第1期   页码 123-131 doi: 10.1007/s11705-014-1415-0

摘要： This paper focuses on modeling and simulation of a post-combustion carbon dioxide capture in a coal-fired power plant by chemical absorption using monoethanolamine. The aim is to obtain a reliable tool for process simulation: a customized rate-based model has been developed and implemented in the ASPEN Plus software, along with regressed parameters for the Electrolyte-NRTL model worked out in a previous research. The model is validated by comparison with experimental data of a pilot plant and can provide simulation results very close to experimental data.

关键词： Absorption     carbon dioxide capture     rate-based model     monoethanolamine scrubbing    

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Economic Growth Model Based on Six Basic Factors of Production—Xu Growth Rate Equation

Shou-bo Xu,Zong-yuan Huang

《工程管理前沿（英文）》 2014年 第1卷 第2期   页码 160-175 doi: 10.15302/J-FEM-2014024

摘要： This paper proposes an economic growth model based on the Six Basic Factors of Production and Xu Growth Rate Equation for the first time, which fills-in the deficits of the New Classical Economic Growth Model based on the Solow Model. The empirical analysis indicates that over the past three decades, the consumption of six basic factors of production had complicated relations with economic growth. In some years, the consumption rate of the basic factors of production was meager, but the economy witnessed relatively rocketing growth rate; in some years, the factors of production consumption rate was very high, but the economy growth rate slowed down. In general, economy grows at the expenses of huge consumption of four factors. There is an obvious characteristic of huge input and low efficiency. The average contribution rate of technological advance peaks in the middle, while it drops down at two ends. Noticeably, since 2004, the technology contribution rate generally shows a downward trend, reasons of which should be explored systematically in aspects like economic policy and industry structure with a view to boost further transformation of the macro-economy scientific growth model.

关键词： six basic factors of production     economic growth model     Xu Growth Rate Equation    

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Modified landfill gas generation rate model of first-order kinetics and two-stage reaction

Jiajun CHEN , Hao WANG , Na ZHANG ,

《环境科学与工程前沿（英文）》 2009年 第3卷 第3期   页码 313-319 doi: 10.1007/s11783-009-0025-4

摘要： This investigation was carried out to establish a new domestic landfill gas (LFG) generation rate model that takes into account the impact of leachate recirculation. The first-order kinetics and two-stage reaction (FKTSR) model of the LFG generation rate includes mechanisms of the nutrient balance for biochemical reaction in two main stages. In this study, the FKTSR model was modified by the introduction of the outflow function and the organic acid conversion coefficient in order to represent the in-situ condition of nutrient loss through leachate. Laboratory experiments were carried out to simulate the impact of leachate recirculation and verify the modified FKTSR model. The model calibration was then calculated by using the experimental data. The results suggested that the new model was in line with the experimental data. The main parameters of the modified FKTSR model, including the LFG production potential (), the reaction rate constant in the first stage (), and the reaction rate constant in the second stage () of 64.746 L, 0.202 d, and 0.338 d, respectively, were comparable to the old ones of 42.069 L, 0.231 d, and 0.231 d. The new model is better able to explain the mechanisms involved in LFG generation.

关键词： landfill gas (LFG)     generation rate model     first-order kinetics     two-stage reaction     outflow function    

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Effect of dilution rate on dynamic and steady-state biofilm characteristics during phenol biodegradation

Veena Bangalore Rangappa, Vidya Shetty Kodialbail, Saidutta Malur Bharthaiyengar

《环境科学与工程前沿（英文）》 2016年 第10卷 第4期 doi: 10.1007/s11783-016-0863-9

摘要： Continuous pulsed plate bioreactor (PPBR) was used for phenol biodegradation. cells immobilized on granular activated carbon was used. Dynamic and steady state biofilm characteristics depend on dilution rate (DR). Lower DR favour phenol degradation and uniform, thick biofilm formation. Exo polymeric substance production in biofilm are favoured at lower dilution rates. Pulsed plate bioreactor (PPBR) is a biofilm reactor which has been proven to be very efficient in phenol biodegradation. The present paper reports the studies on the effect of dilution rate on the physical, chemical and morphological characteristics of biofilms formed by the cells of Pseudomonas desmolyticum on granular activated carbon (GAC) in PPBR during biodegradation of phenol. The percentage degradation of phenol decreased from 99% to 73% with an increase in dilution rate from 0.33 h?1 to 0.99 h?1 showing that residence time in the reactor governs the phenol removal efficiency rather than the external mass transfer limitations. Lower dilution rates favor higher production of biomass, extracellular polymeric substances (EPS) as well as the protein, carbohydrate and humic substances content of EPS. Increase in dilution rate leads to decrease in biofilm thickness, biofilm dry density, and attached dry biomass, transforming the biofilm from dense, smooth compact structure to a rough and patchy structure. Thus, the performance of PPBR in terms of dynamic and steady-state biofilm characteristics associated with phenol biodegradation is a strong function of dilution rate. Operation of PPBR at lower dilution rates is recommended for continuous biologic treatment of wastewaters for phenol removal.

关键词： Biofilm     Exopolymeric substances     Phenol     Dilution rate     Pulsed plate bioreactor    

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标题 作者 时间 类型 操作

Nickel nanopore arrays as promising current collectors for constructing solid-state supercapacitors with ultrahighrate performance

Huaping Zhao, Long Liu, Yaoguo Fang, Ranjith Vellacheri, Yong Lei

期刊论文

of a superhydrophilic/underwater superoleophobic stainless steel mesh for oil/water separation with ultrahigh

期刊论文

Experimental and parametrical investigation of pre-stressed ultrahigh-performance fiber-reinforced concrete

期刊论文

超高压下的极端含能材料

毛河光, 吉诚, 李冰, 刘罡, Eugene Gregoryanz

期刊论文

Synthesis of micro/meso porous carbon for ultrahigh hydrogen adsorption using cross-linked polyaspartic

Jun Wei, Jianbo Zhao, Di Cai, Wenqiang Ren, Hui Cao, Tianwei Tan

期刊论文

Erratum to “Targeted Genotyping of a Whole-Gene Repertoire by an Ultrahigh-Multiplex and Flexible HD-Marker

Pingping Liu,Jia Lv,Cen Ma,Tianqi Zhang,Xiaowen Huang,Zhihui Yang,Lingling Zhang,Jingjie Hu,Shi Wang,Zhenmin Bao,

期刊论文

Activated carbon-hybridized and amine-modified polyacrylonitrile nanofibers toward ultrahigh and recyclable

Fengli Li, Chuang Chen, Yuda Wang, Wenpeng Li, Guoli Zhou, Haoqin Zhang, Jie Zhang, Jingtao Wang

期刊论文

The combined effects of biomass and temperature on maximum specific ammonia oxidation rate in domestic

期刊论文

Use of float consumption rate in resource leveling of construction projects

Atilla DAMCI, Gul POLAT, Firat Dogu AKIN, Harun TURKOGLU

期刊论文

Effect of loading rate on shear strength parameters of mechanically and biologically treated waste

期刊论文

Size-controllable synthesis of monodispersed nitrogen-doped carbon nanospheres from polydopamine for high-rate

期刊论文

Improved rate-based modeling of carbon dioxide absorption with aqueous monoethanolamine solution

Stefania MOIOLI, Laura A. PELLEGRINI, Simone GAMBA, Ben LI

期刊论文

Economic Growth Model Based on Six Basic Factors of Production—Xu Growth Rate Equation

Shou-bo Xu,Zong-yuan Huang

期刊论文

Modified landfill gas generation rate model of first-order kinetics and two-stage reaction

Jiajun CHEN , Hao WANG , Na ZHANG ,

期刊论文

Effect of dilution rate on dynamic and steady-state biofilm characteristics during phenol biodegradation

Veena Bangalore Rangappa, Vidya Shetty Kodialbail, Saidutta Malur Bharthaiyengar

期刊论文